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91.
Konstantinos Chondroudis Debojit Chakrabarty Enos A. Axtell Mercouri G. Kanatzidis 《无机化学与普通化学杂志》1998,624(6):975-979
The reaction of one equivalent of In with a molten flux of (Ph4P)2Se5 and P2Se5 (1 : 2), at 250 °C gave the (Ph4P)[In(P2Se6)] ( I ). Stoichiometric elemental synthesis at 750 °C produced the Cs5In(P2Se6)2 ( II ). The thin, yellow crystals of ( I ), and the irregular, dark orange crystals of ( II ), appear to be air- and water-stable. Compound ( I ) crystallizes in the monoclinic space group C2/c (no. 15) and at 23 °C: a = 23.127(7) Å, b = 6.564(1) Å, c = 19.083(3) Å, β = 97.42(2)°, V = 2873(1) Å3, Z = 4, final R/Rw = 4.4/5.2%. Compound ( II ) crystallizes in the tetragonal space group P42/m (no. 84) and at 23 °C: a = b = 13.886(1) Å, c = 7.597(2) Å, V = 1464.9(3) Å3, Z = 2, final R/Rw = 3.9/5.1%. Compound ( I ) contains infinite [In(P2Se6)]nn– with a structure related to that of K2FeP2Se6. Compound ( II ) contains the discrete [In(P2Se6)2]5– which can be viewed as a fragment of the [In(P2Se6)]nn– chain. 相似文献
92.
Mohamed A. El Mubarak Charikleia Danika Charlyne Cachon Charalambia Korovila Korina Atsopardi Nikolaos Panagopoulos Marigoula Margarity Konstantinos Poulas Gregory B. Sivolapenko 《Biomedical chromatography : BMC》2020,34(2):e4752
A sensitive analytical method was developed and validated for the quantification of cotinine in mouse plasma after exposure to smoke of 0.5, 1.0, and 1.5 commercially available cigarettes, using liquid chromatography tandem mass spectrometry. The method was validated over a linear concentration range of 0.075–20.0 ng/mL with the R2 value being higher than 0.99. Both the precision (coefficient of variation; %) and accuracy (relative error; %) were within acceptable criteria of <15%. The lower limit of quantification (LLOQ) for cotinine was 0.075 ng/mL with sufficient specificity, accuracy, and precision. Following exposure to 0.5, 1.0, and 1.5 cigarette smoke, it was observed that the AUC and the Cmax increased linearly as the doses increased. The pharmacokinetics of cotinine was found linear for the range of 0.5–1.5 commercial cigarette smoke. The quantification of the concentration of cotinine in mouse plasma after smoke exposure will facilitate future behavioral and toxicological experiments in animals and may prove useful in predicting cotinine levels in humans during smoking. 相似文献
93.
Michaela Fecková Ioannis Konstantinos Kalis Dr. Thierry Roisnel Dr. Pascal le Poul Prof. Oldřich Pytela Dr. Milan Klikar Prof. Françoise Robin-le Guen Prof. Filip Bureš Prof. Mihalis Fakis Dr. Sylvain Achelle 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(3):1145-1159
Six pyrimidine-based push–pull systems substituted at positions C2 and C4/6 with phenylacridan and styryl moieties, employing methoxy or N,N-diphenylamino donors, have been designed and synthesized through cross-coupling and Knoevenagel reactions. X-ray analysis confirmed that the molecular structure featured the acridan moiety arranged perpendicularly to the residual π system. Photophysical studies revealed significant differences between the methoxy and N,N-diphenylamino chromophores. Solvatochromic studies revealed that the methoxy derivatives showed dual emission in polar solvents. Time-resolved spectroscopy revealed that the higher energy band involved very fast (<80 ps) fluorescence, whereas the lower energy one included long components (≈30 ns) due to long-lived intramolecular charge-transfer fluorescence. In contrast to N,N-diphenylamino chromophores, the methoxy derivatives also showed aggregation-induced emission in mixtures of THF/water, as well as dual emission in thin films, covering almost the whole visible spectrum with corresponding chromaticity coordinates not far from that of pure white light. These properties render the methoxy derivatives as very promising organic materials for white organic light-emitting diodes. 相似文献
94.
Papadopoulos Charalampos Mimidis Konstantinos Tentes Ioannis Tente Thaleia Anagnostopoulos Konstantinos 《平面色谱法杂志一现代薄层色谱法》2021,34(5):411-418
JPC – Journal of Planar Chromatography – Modern TLC - A set of constituents of the erythrocyte membrane lipidome has been proposed to serve as biomarkers for liver disease and acute... 相似文献
95.
Aristides I Kechriniotis Christos A Tsonos Konstantinos K Delibasis Georgios N Tsigaridas 《理论物理通讯》2020,72(4):45201-63
In this work we study in detail the connection between the solutions to the Dirac and Weyl equations and the associated electromagnetic four-potentials.First,it is proven that all solutions to the Weyl equation are degenerate,in the sense that they correspond to an infinite number of electromagnetic four-potentials.As far as the solutions to the Dirac equation are concerned,it is shown that they can be classified into two classes.The elements of the first class correspond to one and only one four-potential,and are called non-degenerate Dirac solutions.On the other hand,the elements of the second class correspond to an infinite number of four-potentials,and are called degenerate Dirac solutions.Further,it is proven that at least two of these fourpotentials are gauge-inequivalent,corresponding to different electromagnetic fields.In order to illustrate this particularly important result we have studied the degenerate solutions to the forcefree Dirac equation and shown that they correspond to massless particles.We have also provided explicit examples regarding solutions to the force-free Weyl equation and the Weyl equation for a constant magnetic field.In all cases we have calculated the infinite number of different electromagnetic fields corresponding to these solutions.Finally,we have discussed potential applications of our results in cosmology,materials science and nanoelectronics. 相似文献
96.
The design and development of large-scale software projects is a complex endeavor, often facing problems like cost and schedule overruns as well as low quality. Over the last years the management of software development projects has been recognized as the cornerstone point of seeking improvement and solutions. Simulation modeling of the software project process is gaining interest among academics and practitioners, as a method to tackle the complex questions with which relevant enterprises are confronted. It offers support on several issues, such as defining software product development strategies, decision-making regarding process improvement and training, in a time span ranging from a short portion of the life cycle to long term product evolution, with organization-wide implications. The aim of this work is to implement a model simulating a core part of a software project process, enabling the estimation of several project development details such as delivery times and quality metrics. The purpose of the model is to assist project managers in control and monitoring, but also in identifying the best planning alternatives. The model scope covers a portion of the life cycle of an incremental software development venture. 相似文献
97.
A new mechanism for the evolution of primordial magnetic fields is described and analysed. The field evolution is followed from the time of its creation until the epoch of structure and galaxy formation. The mechanism takes into account the turbulent behaviour of the early universe plasma, whose properties determine strongly the evolution of the field configuration. A number of other related issues such as the case of an electroweak plasma are also considered. Finally, as an example, the mechanism is applied to specific models. 相似文献
98.
Kinetics of Lifetime Changes in Bimetallic Nanocatalysts Revealed by Quick X‐ray Absorption Spectroscopy 下载免费PDF全文
Dr. Matthias Filez Dr. Hilde Poelman Dr. Evgeniy A. Redekop Dr. Vladimir V. Galvita Dr. Konstantinos Alexopoulos Dr. Maria Meledina Dr. Ranjith K. Ramachandran Dr. Jolien Dendooven Prof. Christophe Detavernier Prof. Gustaaf Van Tendeloo Dr. Olga V. Safonova Dr. Maarten Nachtegaal Prof. Bert M. Weckhuysen Prof. Guy B. Marin 《Angewandte Chemie (International ed. in English)》2018,57(38):12430-12434
99.
Graphene‐Based Inverted Planar Perovskite Solar Cells: Advancements,Fundamental Challenges,and Prospects 下载免费PDF全文
Dr. Konstantinos Petridis George Kakavelakis Dr. Minas M. Stylianakis Prof. Emmanuel Kymakis 《化学:亚洲杂志》2018,13(3):240-249
Metal halide based perovskite solar cells (PSCs) are considered among the most promising photovoltaic technologies, and already present certified efficiencies that surpass 22 %. The high performance and low fabrication cost make this technology competitive with that of state‐of‐the‐art thin‐film photovoltaics. However, PSCs present some striking disadvantages that hinder their commercialization, including short operational lifetimes, high toxicity, and hysteresis effects, which lower both the performance and long‐term stability of the devices. Herein, work conducted within the last two years is summarized with regard to addressing the challenges of low‐temperature‐processed planar inverted PSCs composed of graphene‐based materials. In addition, critical challenges and the prospects of this field are discussed and some prospects for future research directions are proposed. 相似文献
100.
Bekiari V Pagonis K Bokias G Lianos P 《Langmuir : the ACS journal of surfaces and colloids》2004,20(19):7972-7975
CdS nanoparticles have been synthesized and stabilized in poly(N,N-dimethylacrylamide) hydrogels. The properties of the composite material have been characterized by UV-vis spectroscopy, scanning electron microscopy, X-ray diffraction, thermogravimetric analysis, and steady-state and time-resolved luminescence spectroscopy. This material can be obtained in three different states: swollen, shrunk, and freeze-dried. The swollen and the freeze-dried states correspond to a nanocomposite organic/inorganic (wet or dry) gel containing CdS nanoparticles of approximately 50 nm diameter while the shrunk state is a two-phase system containing CdS crystals, which precipitate forming interesting geometrical shapes. 相似文献